市售乙酰甲胺磷农药的SERS光谱检测

楚雄师范学院学报 ›› 2020, Vol. 35 ›› Issue (3): 33-36.

市售乙酰甲胺磷农药的SERS光谱检测

杨永安^1,2, 李伦^1,2, 张德清^1,2, 司民真^1,2*

1.云南省高校分子光谱重点实验室,云南楚雄 675000;
2.楚雄师范学院光谱应用技术研究所,云南楚雄 675000

收稿日期:2019-11-11 出版日期:2020-05-20 发布日期:2020-12-28
通讯作者: *司民真(1962-),女,博士,楚雄师范学院物理与电子科学学院二级教授,主要从事光谱学研究。E-mail:simninzhen@extcedu.cn
作者简介:杨永安(1973-),男,楚雄师范学院物理与电子科学学院副教授,主要从事光谱学及应用研究。E-mail:yya428@extc.edu.cn
基金资助:
国家自然科学基金项目(NO:11364001);省教育厅基金项目(N0:2015Z187)

Detection of Acephate Pesticide Using Surface-enhanced Raman Spectroscopy (SERS)

YANG Yongan^1,2, LI Lun^1,2, ZHANG Deqing^1,2, SI Minzhen^1,2

1. Key Molecular Spectroscopy Laboratory of Universities of Yunnan Province,Chuxiong Normal University,Chuxiong,Yunnan Province 675000;
2. Institute of Spectroscopy Technology Application,Chuxiong Normal University,Chuxiong,Yunnan Province 675000

Received:2019-11-11 Online:2020-05-20 Published:2020-12-28

摘要/Abstract

摘要： 将恒温法制备的银胶滴在经过处理的载玻片上,制成银膜基底,在该基底获得了不同浓度市售乙酰甲胺磷农药液体的表面增强拉曼光谱,其检测极限为10^-6mol/L。将制备的银胶,组装在毛细管内壁上,制成毛细管-银胶基底,在该基底上获得不同浓度乙酰甲胺磷农药挥发物的表面增强拉曼光谱,其检测极限为10^-6mol/L。本实验所涉及的两种方法可以作为检测市售乙酰甲胺磷液体农药及其挥发物的一种快速、有效的方法。

关键词: 表面增强拉曼光谱, 乙酰甲胺磷农药, 特征峰, 基底

Abstract: In this work,surface-enhanced Raman scattering method based on silver nanoparticles was used to simultaneously detect Acephate pesticide and its volatiles.Acephate pesticide tests at different concentrations indicated that the limit of detection for Acephate pesticide was as low as 1×10^-6 M.Results of detection for volatiles of Acephate pesticide at different concentrations using SERS method revealed that the limit of detection was 1×10^-6 M.Therefore,the finding of this study could offer a promising SERS platform for simultaneous detection of Acephate pesticide and its volatiles.

Key words: surface-enhanced Raman spectroscopy (SERS), Acephate pesticide, characteristic wavenumber, substrate

中图分类号:

TQ455.43

杨永安, 李伦, 张德清, 司民真. 市售乙酰甲胺磷农药的SERS光谱检测[J]. 楚雄师范学院学报, 2020, 35(3): 33-36.

YANG Yongan, LI Lun, ZHANG Deqing, SI Minzhen. Detection of Acephate Pesticide Using Surface-enhanced Raman Spectroscopy (SERS)[J]. Journal of Chuxiong Normal University, 2020, 35(3): 33-36.

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